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W.I.T.C.H
Kelly Stables (Will Vandom): Luisa Palomanes
Candi Milo (Irma Lair): Lina Mendes
Kali Troy (Taranee Cook): Christiane Monteiro
Christel Khalil (Cornelia Hale): Mariana Torres
Liza del Mundo (Hay Lin): Ana Lúcia Menezes
Amigos e Aliados
Greg Cipes (Caleb): Sérgio Cantú
Steve Blum (Blunk): Mário Jorge Andrade
Lauren Tom (Yan Lin): Selma Lopes
Jason Marsden (Matthew "Matt" Olsen): Luiz Sérgio Vieira
Parentes das garotas
Lauren Tom (Susan Vandom-Collins): Miriam Ficher
Candi Milo (Anna Lair): Silvia Goiabeira
Byrne Offutt (Tom Lair): José Luiz Barbeito
Cesar Flores (Christopher 'Chris' Lair): Luciano Monteiro
Mia Korf (Theresa Cook): Izabel Lira
Dorian Harewood (Lionel Cook): Alfredo Martins
Nancy Linary (Elizabeth Hale): Gabriela Bicalho
Alyson Stoner (Lillian Hale): Bárbara Ficher
Rosalind Chao (Joan Lin): Rosane Correa
James Sie (Chen Lin): Mário Cardoso
Ogie Banks (Peter Lancelot Cook): José Leonardo
C.Y.K.E.N
Susan Chesler (Cassidy Chacon): Priscila Amorim
Lauren Tom (Yan Lin Jovem): Flávia Saddy
Kath Soucie (Nerissa jovem): Angélica Borges
C.C.H. Pounder (Kadma jovem): Fernanda Baronne
C.C.H. Pounder (Kadma Starlighter): Vania Alexandre
Vilões
Mitchell Whitfield (Príncipe Phobos): Guilherme Briggs
Serena Berman (Princesa Elyon Brown / Escanor): Jéssica Marina
Dee Bradley Baker (Lord Cedric): Marcelo Garcia
Kath Soucie (Nerissa Crossnic): Maria Helena Pader
Dee Bradley Baker (Frost, o caçador): Maurício Berger
Paul Eiding (Jeek): Sérgio Stern
Raythor: Jorge Vasconcellos
Jeff Bennett (Rastreador): Leonardo José
Grey Griffin / Susan Silo (Miranda): Carol Kapfer
Jason Marsden (Shagon): Philippe Maia
Jim Cummings (Tridart): Márcio Simões
Cree Summer (Ember): Carla Pompílio
Lloyd Sherr (Vathek): Mauro Ramos
Outros Personagens
Loren Lester (Julian): Marco Antonio Costa
Vanessa Marshall (Eleanor Brown/ Miriadel): Mabel Cezar
Mark L. Taylor (Thomas Brown/ Alborn): Hércules Franco
Dee Bradley Baker (Martin Tubbs): Érick Bougleux
Lauren Tom (Alchemy): Bruna Laynes
Cam Clarke (Dean Collins): Alexandre Moreno
Loren Lester (Tynar): Luiz Carlos Persy
Candi Milo (Diretora Knickerbocker): Melise Maia
Michael Reisz (Nigel Ashcroft): Caio César
Aldarn: Marco Ribeiro
Drake: Paulo Vignolo
Sondra: Fernanda Crispim
Bess Grumper: Flávia Fontenelle
Courtney Grumper: Indiane Christine
Elias: Manolo Rey
Senhora Rudolph: Geisa Vidal
Agente Joel McTiennan: Ricardo Juarez
Agente Maria Medina: Guilene Conte